SE446200B - Sett att framstella ett sammansatt arkmaterial, serskilt ett lederliknande material, genom impregnering av ett porost arkmaterial med en vattenhaltig, jonisk polyuretandispersion - Google Patents
Sett att framstella ett sammansatt arkmaterial, serskilt ett lederliknande material, genom impregnering av ett porost arkmaterial med en vattenhaltig, jonisk polyuretandispersionInfo
- Publication number
- SE446200B SE446200B SE7907416A SE7907416A SE446200B SE 446200 B SE446200 B SE 446200B SE 7907416 A SE7907416 A SE 7907416A SE 7907416 A SE7907416 A SE 7907416A SE 446200 B SE446200 B SE 446200B
- Authority
- SE
- Sweden
- Prior art keywords
- ionic
- dispersion
- compound
- polymer
- polyurethane
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims description 33
- 239000002131 composite material Substances 0.000 title claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 58
- 229920000642 polymer Polymers 0.000 claims description 57
- 239000006185 dispersion Substances 0.000 claims description 52
- 229920002635 polyurethane Polymers 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 36
- 150000001875 compounds Chemical class 0.000 claims description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 15
- 239000000701 coagulant Substances 0.000 claims description 13
- 125000005442 diisocyanate group Chemical group 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 230000003381 solubilizing effect Effects 0.000 claims description 11
- 229920005862 polyol Polymers 0.000 claims description 10
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 239000011888 foil Substances 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 150000003077 polyols Chemical class 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 238000007598 dipping method Methods 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 4
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 3
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000004985 diamines Chemical class 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 41
- 239000000758 substrate Substances 0.000 description 29
- 239000002253 acid Substances 0.000 description 27
- -1 decamethylene Chemical group 0.000 description 19
- 239000000203 mixture Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 16
- 239000000243 solution Substances 0.000 description 16
- 230000015271 coagulation Effects 0.000 description 14
- 238000005345 coagulation Methods 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000010985 leather Substances 0.000 description 12
- 229920000742 Cotton Polymers 0.000 description 10
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 239000000835 fiber Substances 0.000 description 10
- 238000005470 impregnation Methods 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 150000007513 acids Chemical class 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 239000012948 isocyanate Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- 150000002513 isocyanates Chemical class 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 5
- 235000011054 acetic acid Nutrition 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 238000000149 argon plasma sintering Methods 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 229920003009 polyurethane dispersion Polymers 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000012975 dibutyltin dilaurate Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920001281 polyalkylene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 2
- 150000004072 triols Chemical class 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- SZBXTBGNJLZMHB-UHFFFAOYSA-N 1-chloro-2,4-diisocyanatobenzene Chemical compound ClC1=CC=C(N=C=O)C=C1N=C=O SZBXTBGNJLZMHB-UHFFFAOYSA-N 0.000 description 1
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920002821 Modacrylic Polymers 0.000 description 1
- HTLZVHNRZJPSMI-UHFFFAOYSA-N N-ethylpiperidine Chemical compound CCN1CCCCC1 HTLZVHNRZJPSMI-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate group Chemical group [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
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- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 150000002483 hydrogen compounds Chemical class 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229940100630 metacresol Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- UHHKSVZZTYJVEG-UHFFFAOYSA-N oxepane Chemical compound C1CCCOCC1 UHHKSVZZTYJVEG-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
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- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
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- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
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- 231100000331 toxic Toxicity 0.000 description 1
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0809—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups
- C08G18/0814—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups containing ammonium groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/904—Artificial leather
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Textile Engineering (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Moulding By Coating Moulds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/940,389 US4171391A (en) | 1978-09-07 | 1978-09-07 | Method of preparing composite sheet material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7907416L SE7907416L (sv) | 1980-03-08 |
| SE446200B true SE446200B (sv) | 1986-08-18 |
Family
ID=25474733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7907416A SE446200B (sv) | 1978-09-07 | 1979-09-06 | Sett att framstella ett sammansatt arkmaterial, serskilt ett lederliknande material, genom impregnering av ett porost arkmaterial med en vattenhaltig, jonisk polyuretandispersion |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US4171391A (en]) |
| JP (1) | JPS5536376A (en]) |
| AU (1) | AU529436B2 (en]) |
| BE (1) | BE878634A (en]) |
| CA (1) | CA1127021A (en]) |
| CH (1) | CH660661GA3 (en]) |
| CS (1) | CS214805B2 (en]) |
| DE (1) | DE2931125C2 (en]) |
| DK (1) | DK150500B (en]) |
| ES (1) | ES479835A1 (en]) |
| FI (1) | FI792762A7 (en]) |
| FR (1) | FR2435341A1 (en]) |
| GB (1) | GB2033445B (en]) |
| IT (1) | IT1116878B (en]) |
| LU (1) | LU81660A1 (en]) |
| NL (1) | NL7906652A (en]) |
| NO (1) | NO154021C (en]) |
| PL (1) | PL121985B1 (en]) |
| SE (1) | SE446200B (en]) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3071445D1 (en) * | 1979-07-24 | 1986-04-03 | Isovolta | Process for preparing sheets of elastomer material and utilisation thereof for sticking |
| US4511605A (en) * | 1980-09-18 | 1985-04-16 | Norwood Industries, Inc. | Process for producing polishing pads comprising a fully impregnated non-woven batt |
| CA1178138A (en) * | 1980-09-18 | 1984-11-20 | John R. Mccartney | Impregnated non-woven sheet material and products produced therewith |
| US4376148A (en) * | 1980-09-18 | 1983-03-08 | Norwood Industries, Inc. | Impregnated non-woven sheet material with ionically solubilized resin |
| US4332710A (en) * | 1981-02-17 | 1982-06-01 | Norwood Industries, Inc. | Thermal coagulation of polyurethane dispersions |
| US4590022A (en) * | 1981-10-26 | 1986-05-20 | Seton Company | Method of forming a moisture permeable polymeric sheet material |
| US4415628A (en) * | 1981-10-26 | 1983-11-15 | Seton Company | Moisture vapor permeable sheet materials |
| US4496624A (en) * | 1982-07-14 | 1985-01-29 | Norwood Industries, Inc. | Fibrous web impregnated with coagulated polyurethane and polyolefin admixture |
| JPS6029782B2 (ja) * | 1983-01-24 | 1985-07-12 | 東洋クロス株式会社 | 透湿性合成皮革の製造法 |
| US4701480A (en) * | 1985-09-23 | 1987-10-20 | Mobay Corporation | Stable, aqueous dispersions of polyurethane-ureas |
| US4690953A (en) * | 1986-03-11 | 1987-09-01 | Seton Company | Method of frothing aqueous ionic polyurethane dispersions and products produced therefrom |
| US4675232A (en) * | 1986-05-19 | 1987-06-23 | Seton Company | Self-release foam laminate |
| DE3622612A1 (de) * | 1986-07-05 | 1988-01-14 | Bayer Ag | Waermesensible polyurethandispersionen |
| DE3633874A1 (de) * | 1986-10-04 | 1988-04-14 | Stockhausen Chem Fab Gmbh | Verfahren zur herstellung mit polyurethan beschichteter textiler flaechengebilde, mit polyurethan beschichtete textile flaechengebilde und ihre verwendung zur herstellung atmungsaktiver und wasserabweisender ausruestungen |
| US5102552A (en) * | 1987-12-16 | 1992-04-07 | Hoechst Celanese Corporation | Membranes from UV-curable resins |
| US4976897A (en) * | 1987-12-16 | 1990-12-11 | Hoechst Celanese Corporation | Composite porous membranes and methods of making the same |
| DE3815159A1 (de) * | 1988-03-09 | 1989-09-21 | Rido Richard Dohse & Sohn | Vorrichtung zum auftrag von vorgeschmolzenen polyurethan-klebstoffen |
| DE4019171A1 (de) * | 1990-06-15 | 1991-12-19 | Henkel Kgaa | Beschichtungsmittel |
| JPH0596377A (ja) * | 1991-10-02 | 1993-04-20 | Matsushita Electric Ind Co Ltd | トーチ焼損防止水回路 |
| DE4418157A1 (de) | 1994-05-25 | 1995-11-30 | Basf Ag | Thermokoagulierbare wässerige Polyurethan-Dispersionen |
| US5801211A (en) * | 1996-10-04 | 1998-09-01 | Cinco, Inc. | Resilient fiber mass and method |
| US6054176A (en) * | 1997-07-22 | 2000-04-25 | Chifa Leather Corp. | Process for making PU air permeable nubuck sheets |
| US5916636A (en) * | 1998-03-17 | 1999-06-29 | Milliken & Company | Method of making a polyurethane suede-like fabric/elastomer composite |
| DE19825453A1 (de) * | 1998-06-06 | 1999-12-09 | Basf Ag | Poromere Kunstleder |
| JP2002533538A (ja) | 1998-12-29 | 2002-10-08 | ザ ダウ ケミカル カンパニー | 機械的に起泡させたポリウレタン分散液から製造されたポリウレタンフォーム |
| BR0111928A (pt) * | 2000-06-23 | 2003-06-10 | Milliken & Co | Composto elastÈmero de tecido preferìvel para revestimento por transferência ou pelìcula |
| US6475562B1 (en) | 2000-06-23 | 2002-11-05 | Milliken & Company | Textile-lastomer composite preferable for transfer on film coating and method of making said composite |
| US6599849B1 (en) | 2000-06-23 | 2003-07-29 | Milliken & Company | Knitted fabric-elastomer composite preferable for transfer or film-coating |
| DE10046239A1 (de) * | 2000-09-19 | 2002-04-04 | Rakoczy Print & Design Oeg Kla | Bandförmiger Gebrauchsgegenstand insbesondere aus Baumvoll-Faser-Flies und Verfahren zur Herstellung des bandförmigen Gegenstandes |
| KR100416414B1 (ko) * | 2000-10-17 | 2004-01-31 | (주)나노폴 | 수분산 폴리우레탄수지 합성피혁의 제조방법 |
| US20030083003A1 (en) * | 2001-10-29 | 2003-05-01 | West Thomas E. | Polishing pads and manufacturing methods |
| DE60328428D1 (de) * | 2002-04-10 | 2009-09-03 | Alcantara Spa | Verfahren zur Herstellung eines mikrofasrigen, wildlederähnlichen Vliesstoffes |
| US8389113B2 (en) * | 2002-09-17 | 2013-03-05 | Ppg Industries Ohio, Inc. | Substrates and articles of manufacture coated with a waterborne 2K coating composition |
| US20070020463A1 (en) * | 2004-12-23 | 2007-01-25 | Trainham James A | Flexible polymer coating and coated flexible substrates |
| JP4570964B2 (ja) * | 2002-12-20 | 2010-10-27 | ダウ グローバル テクノロジーズ インコーポレイティド | 合成皮革を製造するための方法及びそれから製造した合成皮革 |
| US20040209063A1 (en) * | 2003-03-24 | 2004-10-21 | Gallagher Kevin P. | Microporous sheets including a colored base coating and a clear coating |
| US20040191496A1 (en) * | 2003-03-24 | 2004-09-30 | Rearick Brian K. | Coated microporous sheets |
| DE10360368A1 (de) * | 2003-12-22 | 2005-07-21 | Bayer Materialscience Ag | Dispersionen |
| DE102004010456A1 (de) * | 2004-03-01 | 2005-09-22 | Carl Freudenberg Kg | Verfahren zur Herstellung eines lichtechten Syntheseleders und danach hergestellte Produkte |
| US20060063455A1 (en) * | 2004-09-21 | 2006-03-23 | Andover Coated Products, Inc. | Hand-tearable non-elastic tape |
| US20060141234A1 (en) * | 2004-12-23 | 2006-06-29 | Rearick Brian K | Coated compressible substrates |
| DE102006008690A1 (de) | 2006-02-24 | 2007-09-06 | Bayer Materialscience Ag | Dispersionen mit Nanoharnstoffen |
| WO2007143089A2 (en) * | 2006-06-01 | 2007-12-13 | Andover Health Care, Inc. | Foam layer cohesive articles and wound care bandages and methods of making and using same |
| US20080114145A1 (en) * | 2006-11-09 | 2008-05-15 | Richard Czarnecki | Self catalyzing polyurethanes |
| DE102006056956A1 (de) | 2006-11-30 | 2008-06-05 | Benecke-Kaliko Ag | Verbundgebilde mit einer Polyurethanschicht, Verfahren zu deren Hersellung und Verwendung |
| US20090246393A1 (en) * | 2008-03-27 | 2009-10-01 | Ppg Industries Ohio, Inc. | Polycarbodiimides |
| WO2010025350A1 (en) * | 2008-08-28 | 2010-03-04 | Andover Healthcare, Inc. | Silver based antimicrobial compositions and articles |
| DE102009014699A1 (de) | 2009-03-27 | 2010-10-07 | Carl Freudenberg Kg | Verfahren zur Herstellung einer reaktiven Polyurethan-Emulsion |
| KR20150054913A (ko) * | 2012-09-07 | 2015-05-20 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 디지털 프린팅용 패브릭 전처리제 |
| JP2016125155A (ja) * | 2014-12-26 | 2016-07-11 | 日華化学株式会社 | 皮革用材の製造方法及び皮革用材 |
| IT201700117459A1 (it) * | 2017-10-18 | 2019-04-18 | Frumat Srl | Composizione per la realizzazione di un laminato composto da materiale vegetale in particolare scarti di mele e procedimento per la realizzazione di un laminato composto da materiale vegetale in particolare scarti di mele e laminato realizzato mediante detto procedimento |
| WO2019087795A1 (ja) * | 2017-11-01 | 2019-05-09 | Dic株式会社 | 凝固物の製造方法 |
| CN108794705B (zh) * | 2018-06-30 | 2020-05-22 | 江南大学 | 一种改性羧基丁苯胶乳的制备方法及应用 |
| IT202200003428A1 (it) | 2022-02-24 | 2023-08-24 | Lamberti Spa | Metodo di produzione di un materiale similpelle |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3000757A (en) * | 1957-01-28 | 1961-09-19 | Du Pont | Process for coating substrates with a vapor permeable polymeric coating |
| BE614056A (en]) * | 1958-03-25 | |||
| DE1495745C3 (de) * | 1963-09-19 | 1978-06-01 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung wäßriger, emulgatorfreier Polyurethan-Latices |
| GB1101644A (en) * | 1964-02-07 | 1968-01-31 | Kurashiki Rayon Kk | A method of manufacturing sheet materials |
| GB1121651A (en) * | 1964-04-30 | 1968-07-31 | Lantor Ltd | Process for the coagulation of emulsions within a porous substrate |
| US3384502A (en) * | 1964-11-02 | 1968-05-21 | Goodrich Co B F | Process for making permeable sheet material |
| FR1499121A (en]) * | 1964-12-08 | 1968-01-12 | ||
| US3483015A (en) * | 1965-02-03 | 1969-12-09 | Kuraray Co | Method for production of poromeric fibrous sheet materials |
| DE1570602A1 (de) * | 1965-09-03 | 1969-08-14 | Bayer Ag | Verfahren zur Herstellung von waessrigen Polyurethan-Dispersionen |
| DE1635690A1 (de) * | 1966-06-18 | 1971-04-22 | Glanzstoff Ag | Verfahren zur Herstellung lederaehnlicher mikroporoeser Flaechengebilde |
| US3412054A (en) * | 1966-10-31 | 1968-11-19 | Union Carbide Corp | Water-dilutable polyurethanes |
| US3526531A (en) * | 1966-12-01 | 1970-09-01 | Kanebo Ltd | Method for making microporous sheet material |
| US3536518A (en) * | 1967-03-10 | 1970-10-27 | Johnson & Johnson | Method of applying print pattern of resin to fibrous sheet material |
| JPS4743176B1 (en]) * | 1969-07-19 | 1972-10-31 | ||
| JPS4819704B1 (en]) * | 1970-04-13 | 1973-06-15 | ||
| DE2132001C3 (de) * | 1971-06-28 | 1975-04-10 | Roehm Gmbh, 6100 Darmstadt | Verfahren zum Verfestigen von Faservliesen zu einem lederartigen Werkstoff |
| US3895134A (en) * | 1972-05-13 | 1975-07-15 | Teijin Cordley Ltd | Process for producing microporous structures |
| US3849173A (en) * | 1972-06-07 | 1974-11-19 | Johnson & Johnson | Synthetic resin composition and methods of utilizing the same |
| GB1389267A (en) * | 1972-06-14 | 1975-04-03 | Owens Corning Fiberglass Corp | Method for treating glass fibres |
| JPS5067895A (en]) * | 1973-10-22 | 1975-06-06 | ||
| US4011130A (en) * | 1974-09-09 | 1977-03-08 | Minnesota Mining And Manufacturing Company | Leather-like waterlaid sheets containing particulate fillers |
| US4066591A (en) * | 1975-06-02 | 1978-01-03 | Ppg Industries, Inc. | Water-reduced urethane coating compositions |
| JPS5219799A (en) * | 1975-08-08 | 1977-02-15 | Dainippon Ink & Chem Inc | Preparation of aqueous resin solution |
-
1978
- 1978-09-07 US US05/940,389 patent/US4171391A/en not_active Expired - Lifetime
-
1979
- 1979-04-23 ES ES479835A patent/ES479835A1/es not_active Expired
- 1979-04-27 JP JP5159379A patent/JPS5536376A/ja active Granted
- 1979-05-22 IT IT49127/79A patent/IT1116878B/it active
- 1979-07-31 DE DE2931125A patent/DE2931125C2/de not_active Expired
- 1979-08-30 AU AU50448/79A patent/AU529436B2/en not_active Ceased
- 1979-09-04 GB GB7930610A patent/GB2033445B/en not_active Expired
- 1979-09-05 NL NL7906652A patent/NL7906652A/nl not_active Application Discontinuation
- 1979-09-05 CS CS796021A patent/CS214805B2/cs unknown
- 1979-09-05 FI FI792762A patent/FI792762A7/fi not_active Application Discontinuation
- 1979-09-06 LU LU81660A patent/LU81660A1/xx unknown
- 1979-09-06 FR FR7922335A patent/FR2435341A1/fr active Granted
- 1979-09-06 SE SE7907416A patent/SE446200B/sv not_active IP Right Cessation
- 1979-09-06 NO NO792885A patent/NO154021C/no unknown
- 1979-09-06 DK DK372679AA patent/DK150500B/da not_active Application Discontinuation
- 1979-09-06 CH CH805679A patent/CH660661GA3/de unknown
- 1979-09-06 BE BE0/197038A patent/BE878634A/xx not_active IP Right Cessation
- 1979-09-07 CA CA335,171A patent/CA1127021A/en not_active Expired
- 1979-09-07 PL PL1979218173A patent/PL121985B1/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO154021C (no) | 1986-07-02 |
| JPS5536376A (en) | 1980-03-13 |
| PL218173A1 (en]) | 1980-08-25 |
| AU529436B2 (en) | 1983-06-09 |
| IT1116878B (it) | 1986-02-10 |
| PL121985B1 (en) | 1982-06-30 |
| GB2033445B (en) | 1982-12-22 |
| LU81660A1 (fr) | 1979-12-07 |
| NO792885L (no) | 1980-03-10 |
| IT7949127A0 (it) | 1979-05-22 |
| FR2435341B1 (en]) | 1983-10-14 |
| US4171391A (en) | 1979-10-16 |
| FR2435341A1 (fr) | 1980-04-04 |
| GB2033445A (en) | 1980-05-21 |
| AU5044879A (en) | 1980-03-13 |
| SE7907416L (sv) | 1980-03-08 |
| ES479835A1 (es) | 1980-08-16 |
| CH660661GA3 (en]) | 1987-06-15 |
| FI792762A7 (fi) | 1981-01-01 |
| CA1127021A (en) | 1982-07-06 |
| NO154021B (no) | 1986-03-24 |
| DK150500B (da) | 1987-03-09 |
| DE2931125C2 (de) | 1983-09-15 |
| DK372679A (da) | 1980-03-08 |
| DE2931125A1 (de) | 1980-03-20 |
| BE878634A (fr) | 1979-12-31 |
| JPS5756583B2 (en]) | 1982-11-30 |
| CS214805B2 (en) | 1982-06-25 |
| NL7906652A (nl) | 1980-03-11 |
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| NUG | Patent has lapsed |
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